Chemical Name: Sodium azide CAS #: 26628-22-8 Revised By: RRD Toxicology Unit Revision Date: September 24, 2015 (A) Chemical-Physical Properties . Odor: Odorless. The latter is perhaps not so terribly bad at low concentrations since some enterprises (e.g. This is the reason; it is suggested to keep sodium oxide out of the reach of the water. After inflation, a small residue of sodium hydroxide may be left, in addition to lubricants such as corn starch or talc. Get global suppliers, vendor, prices, . If the decomposition takes place in air, lead(II) oxide will also form. In b iochemistry, it inhibits cytochrome oxidase by binding irreversibly to the heme cofactor in a process similar to the action of carbon monoxide. Solubility: 42 g/100 g water @ 17C (63F) Specific Gravity: 1.85 pH: No information found. It’s a soft metal, reactive and with a low melting point, with a relative density of 0,97 at 20ºC (68ºF). LABORATORY CHEMICAL SAFETY SUMMARY: SODIUM AZIDE Substance Sodium azide (Hydrazoic acid, sodium salt) CAS 26628-22-8 Formula NaN 3 Physical Properties Colorless crystalline solid mp >275 °C (decomposes) Readily soluble in water (41.7 g/100 mL at 17 °C) Odor Odorless solid Toxicity Data LD 50 oral (rat) 27 mg/kg LD 50 skin (rabbit) 20 mg/kg TLV-TWA (ACGIH) 0.29 mg/m3 (ceiling) Major … MD. Relevant identified uses of the substance or mixture and uses advised … It is not explosive except when heated near its decomposition temperature (300°C) or reacted with metals; heating sodium azide should be avoided. Sodium Oxide produces Sodium Hydroxide when it reacts with water. It is a white crystalline solid. Sodium - Sodium - Chemical properties: Generally, elemental sodium is more reactive than lithium, and it reacts with water to form a strong base, sodium hydroxide (NaOH). It is highly toxic and presents a severe explosion risk when stunned or heated. While other azides have their uses in creating explosives and aiding medicine—sodium azide, for example, plays a role in the world of medical devices—azidoazide azide is entirely the realm of experimental chemistry. Properties. Compare Products: Select up to 4 products. The products are nitrogen and sodium. Product identifier Sodium azide Substance / mixture substance Chemical name sodium azide CAS number 26628-22-8 Index number 011-004-00-7 EC (EINECS) number 247-852-1 Registration number 01-2119457019-37-xxxx 1.2. When mixed with acid or water, sodium azide may rapidly change into a toxic and explosive gas (hydrogen azide, HN3 or hydrazoic acid). : S227I-1; S227I-25; S227I-100; S227I-500; S227I-500LC CAS-No 26628-22-8 Synonyms Sodium salt of hydrazoic acid; Smite Recommended Use Laboratory chemicals. Can Sodium Bicarbonate be taken for mycotoxin-induced diseases? PHYSICAL PROPERTIES OF SODIUM AZIDE Page in Marketizer.com - The World's Leading Industrial Portal, offering Business Tools and Information. What is known is that sodium azide is water-soluable. Over a period of time, sodium azide may react with copper, lead, brass, or solder in plumbing systems to form an accumulation of the highly explosive compounds of lead azide and copper azide. 2NaN 3 (s) 2Na(l) + 3N 2 (g) Calculate the mass, in g, of sodium azide needed to produce 144 dm3 of nitrogen using the following steps. It's a good thing, too. Just how sodium azide is metabolized is unclear. Sodium bicarbonate is used in ER settings to neutralize overdoses and poisoning, and has antifungal properties and mold is a fungus. Search results for 1S/BrO/c1-2/q-1 at Sigma-Aldrich. Chemistry Formulas . Sodium azide is also the chief chemical used to inflate safety airbags in automobiles. Sodium. Calculated spectral properties of perylene orange, perylene red, and their complex with sodium azide We'd rather leave this chemical to the professionals. It is considered a safer replacement for hydrazoic acid in many reactions. Lead azide is a white solid, poorly soluble in water and ammonia, but very soluble in acetic acid, more so if hot. At 200 ppm, sodium azide not only sterilizes the soil -- killing soil bacteria and fungi -- but also changes soil chemistry. Product Name Sodium azide Cat No. Sodium Azide 26628-22-8 90 - 100% 3. Sodium azide reacts with various metals to form shock-sensitive compounds. Premium Questions. The signal from the deceleration sensor ignites the gas-generator mixture by an electrical impulse, creating the high-temperature condition necessary for NaN 3 to decompose. *Please select more than one item to compare Properties Chemical. However, sodium azide isn't found in many air bags these days — its nasty properties caused it to be phased out in the 1990s — but in its time, it saved a lot of people. Physical and Chemical Properties Appearance: Colorless crystals. Search results for Sodium azide (<99%) at Sigma-Aldrich. Do any physicians ... View answer. Trimethylsilyl azide is commercially available. It is an explosive. It is soluble in water or fluid ammonia, slightly solvable in alcohols, and inexplicable in ether. It is a very reactive and highly toxic chemical. Chemical element, symbol: Na, atomic number: 11 and atomic weight 22,9898. Sodium azide (NaN 3) can decompose at 300 o C to produce sodium metal (Na) and nitrogen gas (N 2). Synthesis and Magnetic Properties of Nd(Fe,M) 12 (M=Mo,Ti) and their Compounds Nitrided by Chemical Reaction with Sodium Azide (NaN 3 ) February 2001 Key Engineering Materials 189-191:655-660 When a car airbag is used the sodium azide, NaN 3, decomposes. The equation for the decomposition of sodium azide is shown. In Comprehensive Chemical Kinetics, 1980 (b) Sodium azide. Section 7 - Handling and Storage Handling: Minimize dust generation and accumulation. Nitrogen gas is produced upon NaN 3 detonation. (b) Some car airbags contain sodium azide. The odor of the gas may not provide sufficient warning of exposure. How fast? Compare Products: Select up to 4 products. Sodium azide is a white crystalline powder consisting of positive sodium ion and negative azide ions. "Practically nothing is known about the environmental chemistry or biology of azide," Betterton said. The azide ion is the 'interesting' part of the molecule and is the part which is responsible for much of the molecules' reactivity. Do not let this chemical enter the environment. The chemical formula is: Na 2 O + H 2 O > 2NaOH. Sodium azide is used as a source of azide anion which is a strong nucleophile that readily displaces suitable leaving groups. The nitrogen gas that is generated then fills the airbag. BuyersGuideChem provides reliable information about Sodium azide (26628-22-8) like chemical properties, structure, melting point boiling point, density, molecular formula, molecular weight, physical properties, toxicity information. Sodium Azide is a colorless, unscented, transparent solid or solution. Its chemistry is well explored. This breakdown of sodium azide is very fast. Chemical properties of Sodium Oxide. I have mycotoxicosis - toxic mold poisoning . Sodium azide is used as a chemical preservative in hospitals and laboratories. The azide group is made up three nitrogen atoms joined together. Part 201 Value Updated Value Reference Source Comments Molecular Weight (g/mol) 65.01 EPI EXP Physical State at ambient temp Solid MDEQ Melting Point (˚C) 275.00 Pub Chem EXP Boiling Point (˚C) NA Solubility (ug/L) NA Vapor Pressure (mmHg at … *Please select more than one item to compare Sodium azide decomposes oexplosively upon shock, concussion, heating (>275 C), or friction. View More Information about: Sodium azide More Information about Buying, Selling and doing Business with Sodium azide Suppliers / Providers of Sodium azide (50) Requests for Sodium azide (10) Customers or Buyers of Sodium azide Offers from … In one case, sodium azide was poured into a drain, where it exploded and the toxic gas was inhaled (breathed in). It can be detonated by an electric spark. PROPERTIES Sodium azide is a common preservative of samples and stock solutions in laboratories and a useful reagent in synthetic work. Uses advised against Food, drug, pesticide or biocidal product use Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, … (6), n = 2], though the range of α over which the fit could be regarded as satisfactory varied with reactant mass owing to the influence of product gas pressure on the ease of volatilization of the sodium metal formed. Sodium azide is useful in the preparation of Agricultural Chemical (Insecticide, Fungicide, bactericide, wood preservative, Herbicide). Evacuate unnecessary personnel. It may be prepared by the reaction of trimethylsilyl chloride and sodium azide: TMSCl + NaN 3 → TMSN 3 + NaCl (TMS = (CH 3) 3 Si) Applications. So, I would be more than happy to learn about proper alternatives to sodium azide. Sodium azide SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Do not flush down the drain. DESCRIPTION: Sodium azide exists as an odorless white solid. However, the decomposition is not as smooth as that of sodium azide, and may explode. Sodium azide is the chemical that makes airbags work. The vacuum decomposition of sodium azide obeyed the Avrami—Erofe'ev equation [eqn. An airbag is inflated with nitrogen gas at a velocity of about 200 miles per hour – or in 20-30 milliseconds! Accidents have occurred in these settings. Gently heating lead(II) azide will give off nitrogen gas and leave behind pure lead. Sodium azide is also used in detonators and other explosives. It contains sodium and azide ions.It reacts with acids to produce hydrazoic acid.It can be destroyed by reacting it with nitrous acid.This reaction produces nitric oxide, nitrogen, and sodium hydroxide.It is a powerful reducing agent, which makes it explosive. Sodium azide is used in agriculture (farming) for pest control. Physical and Chemical Properties (5.11, 5.12) Hydrazoic acid (CAS No. Chemical properties of sodium azide . When mixed with water or an acid it changes rapidly to a toxic gas with a sharp odor as well as releasing hydrazoic acid (HN3). Azide functionalized molecules can undergo a number of transformations including copper-catalyzed [2+3] cyclocondensation with terminal alkynes and the Staudinger Reaction.Sodium azide is also commonly used as a preservative in many biochemical … This reaction is violent due to highly exothermic abilities. Chemical Reaction Formula Atomic Mass Formula Chemical Formula Enthalpy Formula Entropy Formula Molality Formula Molar Mass Formula Molarity Formula Structural Formula Molecular Formula Chemical Compound Formula Chemical Equilibrium Formula Normality Formula Photosynthesis Formula Grams to Moles Conversion Formula Moles to Grams Conversion Formula … Physical. In an airbag, electricity sets off a detonation reaction that leads to the decomposition of sodium azide, producing nitrogen gas as one of the products. Laboratory Uses. Sodium is ordinarily quite reactive with air, and the reactivity is a function of the relative humidity, or water-vapour content of the air.